Prof. Hirohisa Ohmiya (Original papers, Reviews)

Original papers

  1. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes
    Ishii, T.; Ota, K.; Nagao, K.; Ohmiya, H.
    J. Am. Chem. Soc. 2019141, 14073–14077.
    DOI: 10.1021/jacs.9b07194

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  2. Synergistic N-Heterocyclic Carbene/Palladium Catalyzed Aldehyde Acylation of Allylic Amines
    Ohnishi, N.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    Asian. J. Org. Chem. 2019, 8, 1133–1135.
    DOI: 10.1002/ajoc.201900303

  3. Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand
    Imai, K.; Takayama, H.; Murayama, H., Ohmiya, H.; Shimizu Y.; Sawamura, M.
    Org. Lett. 2019, 21, 1717–1721.
    DOI: 10.1021/acs.orglett.9b00276
  4. N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes
    Ishii, T.; Kakeno, Y.; Nagao, K.; Ohmiya, H.
    J. Am. Chem. Soc. 2019141, 3854–3858.
    DOI: 10.1021/jacs.9b00880

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  5. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Allylation of Aldehydes with Allylic Carbonates
    Takemoto, S.; Ishii, T.; Yasuda, S.; Ohmiya, H.
    Bull. Chem Soc. Jpn. 201992, 937–940 (Selected Paper).
    DOI: 10.1246/bcsj.20190012
  6. Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis
    Takeda, M.; Mitsui, A.; Nagao, K.; Ohmiya, H.
    J. Am. Chem. Soc. 2019141, 3664–3669 (Supplementary Cover).
    DOI: 10.1021/jacs.8b13309


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  7. Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions
    Yabushita, K.; Yuasa, A.; Nagao, K.; Ohmiya, H.
    J. Am. Chem. Soc. 2019141, 113–117.
    DOI: 10.1021/jacs.8b11495

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  8. Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis
    Haruki, H.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    Chem. Eur. J. 2019, 25, 724–727 (Front Cover, Cover Profile).
    DOI: 10.1002/chem.201805955


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  9. Synergistic Palladium/Copper-Catalyzed Csp3–Csp2 Cross-Couplings Using Aldehydes As Latent α-Alkoxyalkyl Anion Equivalents. 
    Takeda, M.; Yabushita, K.; Yasuda, S.; Ohmiya, H. 
    Chem. Commun. 201854, 6776–6779 (Back Cover).
    Emerging Investigators 2018 Issue 
    DOI: 10.1039/c8cc01055b 
      
  10. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates. 
    Yasuda, S.; Ishii, T.; Takemoto, S.; Haruki, H.; Ohmiya, H. 
    Angew. Chem. Int. Ed. 201857, 2938–2942. 
    DOI: 10.1002/anie.201712811 

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  11. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
    Nagao, N.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2018, 20, 1861–1865.
    DOI: 10.1021/acs.orglett.8b00390
  12. Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of  α-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions
    Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M.
    Chem. Sci. 2018, 9, 3484–3493.
    DOI: 10.1039/C8SC00527C
  13. Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation 
    Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M. 
    Chem. Lett. 201847, 632–635..
    DOI: 10.1246/cl.180147
  14. Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates with a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes
    Yasuda, Y.; Ohmiya, H.; Sawamura, M. 
    Synthesis 2018, 50, 2235–2246. 
    DOI: 10.1055/s-0036-1591548
  15. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted γ-Borylallylboranes
    Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 201857, 3196–3199. 
    DOI: 10.1002/anie.201712351
  16. Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand.
    Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M. 
    Chem. Eur. J. 201723, 8400–8404.
    DOI: 10.1002/chem.201702070
  17. Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides 
    Hojoh, K.; Ohmiya, H.; Sawamura, M. 
    J. Am. Chem. Soc. 2017139, 2184-2187. 
    DOI: 10.1021/jacs.6b12881
  18. Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand 
    Yasuda, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2016 , 55, 10816–10820.
    DOI: 10.1002/anie.201605125
  19. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates 
    Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2016 , 18, 1706–1709.
    DOI: 10.1021/acs.orglett.6b00677
  20. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen 
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Organometallics 2016 , 35, 1354–1357.
    DOI: 10.1021/acs.organomet.6b00126
  21. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles 
    Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M.
    Angew. Chem. Int. Ed. 2016 , 55, 4777–4780.
    DOI:10.1002/anie.201600619
  22. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates.
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Beilstein J. Org. Chem. 2015 , 11, 2444–2450.
    DOI: 10.3762/bjoc.11.265
  23. Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki-Miyaura Cross-coupling of Chloroarenes.
    Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M.
    ACS Catal. 2015 , 5, 7254–7264.
    DOI: 10.1021/acscatal.5b00904
  24. Synthesis of 1,1-Diborylalkenes through a Bronsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
    Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2015 , 54, 15859–15862.
    DOI: 10.1002/anie.201509218
  25. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.
    Tetrahedron 2015 , 71, 6519–6533.
    DOI:10.1016/j.tet.2015.05.048
  26. Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes.
    Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M.
    Chem. Eur. J. 2015 , 21, 9666–9670.
    DOI: 10.1002/chem.201501055
  27. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes.
    Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2015 , 17, 2039–2041.
    DOI: 10.1021/acs.orglet.5b00758
  28. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis.
    Nagao, K.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2015 , 17, 1304–1307.
    DOI: 10.1021/acs.orglett.5b00305
  29. Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles.
    Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2014 , 136, 13932–13939.
    DOI: 10.1021/ja5084333
  30. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes.
    Nagao, K.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2014 , 136, 10605–10608.
    DOI: 10.1021/ja506310v
  31. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2014 , 53, 4954–4958 (Hot Paper).
    DOI: 10.1002/anie.201402386
  32. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide.
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2013 , 52, 11620–11623.
    DOI: 10.1002/anie.201305973
  33. Cooperative Catalysis of Metal and O-H・・・O/sp3-C-H・・・O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes.
    Ishii, T.; Watanabe, R.; Moriya, T.; Ohmiya, H,; Mori, S.; Sawamura, M.
    Chem. Eur. J. 2013 , 19, 13547–13553.
    DOI: 10.1002/chem.201301280
  34. Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes.
    Makida, Y.; Takayama, Y.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2013 , 52, 5350–5354.
    DOI: 10.1002/anie.201300785
  35. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters.
    Ito, H.; Harada, A.; Ohmiya, H.; Sawamura, M.
    Adv. Synth. Catal. 2013 , 355, 647–652.
    DOI: 10.1002/adsc.201200949
  36. Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes.
    Shido, Y.; Yoshida M.; Tanabe, M.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2012 , 134, 18573–18576.
    DOI: 10.1021/ja3093955
  37. Conjugate Reduction of α,β-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane-Copper Complex.
    Kawamorita, S.; Yamazaki, K.; Ohmiya, H.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2012 , 354, 3440–3444.
    DOI: 10.1002/adsc.201200555
  38. Rh-Catalyzed Borylation of N-Adjacent C(sp3)-H Bonds with a Silica-Supported Triarylphosphine Ligand.
    Kawamorita, S.; Miyazaki, T.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2012 , 134, 12924-12927.
    DOI: 10.1021/ja305694r
  39. Synthesis of Allenylsilanes through Copper-Catalyzed γ-Selective Coupling between γ-Silylated Propargylic Phosphates and Alkylboranes.
    Yokobori, U.; Ohmiya, H.; Sawamura, M.
    Organometallics 2012 , 31, 7909-7913.
    DOI: 10.1021/om300552f
  40. Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex.
    Yoshida, M.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2012, 134, 11896-11899.
    DOI: 10.1021/ja304481a
  41. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes.
    Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2012 , 134, 8982-8987.
    DOI: 10.1021/ja302520h
  42. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    Nagao, K.; Ohmiya, H.; Sawamura, M.
    Synthesis 2012, 44, 1535-1541.
    DOI: 10.1055/s-0031-1290818
  43. Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation.
    Makida, Y.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2012, 51, 4122-4127.
    DOI: 10.1002/anie.201200809
  44. Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates.
    Yang, M.; Yokokawa, N.;Ohmiya, H.; Sawamura, M.
    Org. Lett. 2012, 14, 816-819.
    DOI: 10.1021/ol2033465
  45. Efficient Preparation of β-Branched γ,δ -Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal.
    Li, D.; Ohmiya, H.; Sawamura, M. Synthesis 2012, 44, 1304-1307.
    DOI: 10.1055/s-0031-1289712
  46. Rh-Catalyzed Ortho-Selective C-H Borylation of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands.
    Kawamorita, S.; Miyazaki, T.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    J. Am. Chem. Soc. 2011, 133, 19310-19313.
    DOI: 10.1021/ja208364a
  47. General Approach to Allenes through Copper-Catalyzed gannma γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes.
    Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    Org. Lett. 2011, 13, 6312-6315.
    DOI: 10.1021/ol202866h
  48. Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with Silica-Supported Compact Phosphane Ligand.
    Kawamorita, S.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    Angew. Chem. Int. Ed. 2011, 50, 8363-8366 (VIP).
    DOI: 10.1002/anie.201103224
  49. Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold-Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo-dig Cyclization.
    Ito, H.; Harada, T.; Ohmiya, H.; Sawamura, M.
    Beilstein. J. Org. Chem. 2011, 7, 951-959.
    DOI: 10.3762/bjoc.7.106
  50. Copper-Catalyzed Conjugate Additions of Alkylboranes to Aryl α,β-Unsaturated Ketones.
    Ohmiya, H.; Shido, Y.; Yoshida, M.; Sawamura, M.
    Chem. Lett. 2011, 40, 928-930.
    DOI: 10.1246/cl.2011.928
  51. Copper-Catalyzed γ-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals.
    Li, D.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2011, 133, 5672-5675.
    DOI: 10.1021/ja111645q
  52. Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes.
    Ohmiya, H.; Tanabe, M.; Sawamura, M.
    Org. Lett. 2011, 13, 1086-1088.
    DOI: 10.1021/ol103128x
  53. Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl α,β-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes.
    Ohmiya, H.; Yoshida, M.; Sawamura, M.
    Org. Lett. 2011, 13, 482-485.
    DOI: 10.1021/ol102819k
  54. Sulfonamidoquinoline-Palladium(II) Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids.
    Makida, Y.; Ohmiya, H.; Sawamura, M.
    Chem. Asian J. 2011, 6, 410-414.
    DOI: 10.1002/asia.201000721
  55. Construction of Methylenecycloheptane Frameworks through 7-Exo-dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex.
    Ito, H.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2010, 12, 4380-4383.
    DOI: 10.1021/ol101860j
  56. Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex.
    Yamazaki, K.; Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2010, 12, 3978-3981.
    DOI: 10.1021/ol101493m
  57. Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes.
    Ohmiya, H.; Yoshida, M.; Sawamura, M.
    Synlett 2010, 2136-2140.
    DOI: 10.1055/s-0030-1258527
  58. Synthesis of α-Arylated Allylsilanes through Palladium-Catalyzed γ-Selective Allyl-Aryl Coupling.
    Li, D.; Tanaka, T.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2010, 12, 3344-3347.
    DOI: 10.1021/ol101114r
  59. Copper-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates.
    Ohmiya, H.; Yokokawa, N.; Sawamura, M.
    Org. Lett. 2010, 12, 2438-2440.
    DOI: 10.1021/ol100841y
  60. Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex.
    Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    J. Org. Chem. 2010, 75, 3855-3858.
    DOI: 10.1021/jo100352b
  61. Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates.
    Ohmiya, H.; Yang, M.; Yamauchi, Y.; Ohtsuka, Y.; Sawamura, M.
    Org. Lett. 2010, 12, 1796-1799.
    DOI: 10.1021/ol100405k
  62. Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    J. Am. Chem. Soc. 2010, 132, 2895-2897.
    DOI: 10.1021/ja9109105
  63. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids.
    Ohmiya, H.; Makida, Y.; Li, D.; Tanabe, M.; Sawamura, M.
    J. Am. Chem. Soc. 2010, 132, 879-889.
    DOI: 10.1021/ja9092264
  64. General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate.
    Ohmiya, H.; Ito, H.; Sawamura, M.
    Org. Lett. 2009, 11, 5618-5620.
    DOI: 10.1021/ol902339a
  65. Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents. 
    Ohmiya, H.; Moriya, T.; Sawamura, M.
    Org. Lett. 2009, 11, 2145-2147.
    DOI: 10.1021/ol9007712
  66. Directed ortho-Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System.
    Kawamorita, S.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    J. Am. Chem. Soc. 2009, 131, 5058-5059.
    DOI: 10.1021/ja9008419
  67. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids.
    Ohmiya, H.; Makida, Y.; Tanaka, T.; Sawamura, M.
    J. Am. Chem. Soc. 2008, 130, 17276-17277.
    DOI: 10.1021/ja808673n
  68. Cyclization of Non-Terminal Alkynic β-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand.
    Ito, H.; Makida, Y.; Ochida, A.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2008, 10, 5051-5054.
    DOI: 10.1021/ol802079r
  69. Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes.
    Hamasaka, G.; Kawamorita, S.; Ochida, A.; Akiyama, R.; Hara, K.; Fukuoka, A.; Asakura, K.; Chun, W. J.; Ohmiya, H.; Sawamura, M.
    Organometallics 2008, 27, 6495-6506.
    DOI: 10.1021/om800683g
  70. Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System.
    Kawamorita, S.; Hamasaka, G.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    Org. Lett. 2008, 10, 4697-4700.
    DOI: 10.1021/ol801996r
  71. Synthesis, Properties and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane.
    Ochida, A.; Hamasaka, G.; Yamauchi, Y.; Kawamorita, S.; Oshima, N.; Hara, K.; Ohmiya, H.; Sawamura, M.
    Organometallics 2008, 27, 5494-5503.
    DOI: 10.1021/om8005728
  72. Cobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with Dimethylphenylsilylmethylmagnesium Chloride.
    Kobayashi, T.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    J. Am. Chem. Soc. 2008, 130, 11276-11277.
    DOI: 10.1021/ja804277x
  73. Silver-Catalyzed Benzylation and Allylation Reactions of Alkyl Halides with Grignard Reagents.
    Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Org. Lett. 2008, 10, 969-971.
    DOI: 10.1021/ol800038a
  74. Generation of Rhodium Enolates via Retro-Aldol Reaction and Its Application to Regioselective Aldol Reaction.
    Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Tetrahedron Lett. 2008, 49, 2388-2390.
    DOI: 10.1016/j.tetlet.2008.02.062
  75. Alpha Olefins as Alkenylmetal Equivalents in Catalytic Conjugate Addition Reactions.
    Ho, C.-Y.; Ohmiya, H.; Jamison, T. F.
    Angew. Chem. Int. Ed. 2008, 47, 1893-1895.
    DOI: 10.1002/anie.200705163
  76. N-Heterocyclic Carbene Ligands in Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with Grignard Reagents.
    Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Org. Lett. 2007, 9, 1565-1567.
    DOI: 10.1021/ol070392f
  77. Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with Grignard Reagents and Their Application to the Synthesis of 1,3-Diols.
    Someya, H.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Tetrahedron 2007, 63, 8609-8618.
    DOI: 10.1016/j.tet.2007.04.083
  78. Chromium-Catalyzed Arylmagnesiation of Alkynes.
    Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Org. Lett. 2007, 9, 1569-1571.
    DOI: 10.1021/ol0703938
  79. Nickel-Catalyzed Carbometalation Reactions of [2-(1-Propynyl)phenyl]methanol with 1-Alkenylmagnesium Reagents.
    Murakami, K.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Chem. Lett. 2007, 36, 1066-1067.
    DOI: 10.1246/cl.2007.1066
  80. A New Approach to 4-Aryl-1,3-butanediols by Cobalt-Catalyzed Sequential Radical Cyclization/Arylation Reaction of Silicon-tethered 6-Iodo-1-hexene Derivatives.
    Someya, H.; Kondoh, A.; Sato, A.; Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Synlett 2006, 18, 3061-3064.
    DOI: 10.1055/s-2006-951508
  81. Cobalt(diamine)-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Arylmagnesium Reagents: Stereoselective Constructions of Arylated Asymmetric Carbons and Application to Total Synthesis of AH13205.
    Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    J. Am. Chem. Soc. 2006, 128, 1886-1889.
    DOI: 10.1021/ja057560o
  82. Cobalt-Mediated Cross-Coupling Reactions of Primary and Secondary Alkyl Halides with 1-Trimethylsilylethenyl- and 2-Trimethylsilylethynylmagnesium Reagents.
    Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Org. Lett. 2006, 8, 3093-3096.
    DOI: 10.1021/ol0611144
  83. Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents and Their Application to Sequential Radical Cyclization/Cross-Coupling Reactions.
    Ohmiya, H.; Wakabayashi, K.; Yorimitsu, H.; Oshima, K.
    Tetrahedron 2006, 62, 2207-2213.
    DOI: 10.1016/j.tet.2005.12.013
  84. Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides: A Complement to the Heck Reaction.
    Affo, W.; Ohmiya, H.; Fujioka, T.; Ikeda, Y.; Nakamura, T.; Yorimitsu, H.; Oshima, K.; Imamura, Y.; Mizuta, T.; Miyoshi, K.
    J. Am. Chem. Soc. 2006, 128, 8068-8077.
    DOI: 10.1021/ja061417t
  85. Cobalt-Catalyzed Syn-Hydrophosphination of Alkynes.
    Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Angew. Chem. Int. Ed. 2005, 44, 2368-2370.
    DOI: 10.1002/anie.200500255
  86. Regio- and Stereoselective Approach to 1,2-Di- and 1,1,2-Trisilylethenes by Cobalt-Mediated Reaction of Silyl-Substituted Dibromomethanes with Silylmethylmagnesiums.
    Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Angew. Chem. Int. Ed. 2005, 44, 3488-3490.
    DOI: 10.1002/anie.200500576
  87. Cobalt-Catalyzed Cross-Coupling Reaction of Chloropyridines with Grignard Reagents.
    Ohmiya, H.; Yorimitsu, H.; Oshima, K.
    Chem. Lett. 2004, 33, 1240-1241.
    DOI: 10.1246/cl.2004.1240
  88. Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Allylic and Benzylic Grignard Reagents and Their Application to Tandem Radical Cyclization/Cross-Coupling Reaction.
    Ohmiya, H.; Tsuji, T.; Yorimitsu, H.; Oshima, K. Chem. Eur. J. 2004, 10, 5640-5648.
    DOI: 10.1002/chem.200400545
  89. Novel Synthesis of 5-Thio-hexopyranoside: Preparation of 5-Thio-D- and L-glucose and 1,6-Anhydro-5-thio-L- and D-altrose.
    Uenishi, J. i.; Ohmiya, H.
    Tetrahedron 2003, 59, 7011-7022.
    DOI: 10.1016/S0040-4020(03)00864-0
  90. Studies on Stereoselective Sonogashira Coupling of 1,1-Dibromo-1-alkene. Uenishi, J. i.; Matsui, K.; Ohmiya, H.
    J. Organomet. Chem. 2002 , 653, 141-149.
    DOI: 10.1016/S0022-328X(02)01262-7

Reviews

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    大宮寛久
    ファインケミカル, 2019, 48, 41–44.
  2. ある若手PIの回想
    大宮寛久
    有機合成化学協会誌 2019, 77, 732–734.
    Message from Young Principal Researcher (MyPR)
  3. ヘテロ芳香環の位置選択的官能基化
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    化学, 201873, 66–67.
  4. アルデヒドを求核剤原料として用いる極性転換型反応
    大宮寛久 
    Organometallic News 2018, 49–52.
  5. 銅触媒の機能化に基づく高選択的合成反応の開発 
    大宮寛久・澤村正也
    化学工業(特集「戦略的触媒開発と応用」),2016, 67, 361-366.
  6. 有機金属ハイライト「 1,2- メタレート転位の新展開」
    大宮寛久
    Organometallic News , 2016, 34
  7. Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes.
    Ohmiya, H.; Sawamura, M.
    J. Synth. Org. Chem. Jpn. 2014 , 72 (Special Issue in English), 1207-1217.
  8. 飛翔する若手研究者「アリル化の反応位置を究める」
    大宮寛久
    化学と工業, 2011, 64-8, pp 627.
  9. 注目の論文「定説への挑戦」
    大宮寛久
    化学, 2009, 64, 64-65.
  10. 海外研究室レポート「 MIT Timothy F. Jamison 研究室」
    大宮寛久
    Organometallic News 2009 , 85, 106-107.