Dr. Kazunori Nagao (Original papers, Reviews)

Original papers

1. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes
   Ishii, T.; Ota, K.; Nagao, K.; Ohmiya, H.
   J. Am. Chem. Soc. 2019, 141, 14073–14077.
   DOI: 10.1021/jacs.9b07194
2. Synergistic N-Heterocyclic Carbene/Palladium Catalyzed Aldehyde Acylation of Allylic Amines
   Ohnishi, N.; Yasuda, S.; Nagao, K.; Ohmiya, H.
   Asian. J. Org. Chem. 2019, 8, 1133–1135.
   DOI: 10.1002/ajoc.201900303
   
3. N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes
   Ishii, T.; Kakeno, Y.; Nagao, K.; Ohmiya, H.
   J. Am. Chem. Soc. 2019, 141, 3854–3858.
   DOI: 10.1021/jacs.9b00880
4. Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis
   Takeda, M.; Mitsui, A.; Nagao, K.; Ohmiya, H.
   J. Am. Chem. Soc. 2019, 141, 3664–3669.
   DOI: 10.1021/jacs.8b13309
5. Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions
   Yabushita, K.; Yuasa, A.; Nagao, K.; Ohmiya, H.
   J. Am. Chem. Soc. 2019, 141, 113–117.
   DOI: 10.1021/jacs.8b11495
6. Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis
   Haruki, H.; Yasuda, S.; Nagao, K.; Ohmiya, H.
   Chem. Eur. J. 2019, 25, 724–727 (Front Cover, Cover Profile).
   DOI: 10.1002/chem.201805955
7. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
   Nagao, N.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
   Org. Lett. 2018, 20, 1861–1865.
   DOI: 10.1021/acs.orglett.8b00390
8. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted γ-Borylallylboranes
   Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
   Angew. Chem. Int. Ed. 2018, 57, 3196–3199. 
   DOI: 10.1002/anie.201712351
9. Photoredox-Catalyzed Deuteration and Tritiation of Pharmaceutical Compounds
   Loh, Y.Y*.; Nagao, K*.; Hoover, A. J.; Hesk, D.; Rivera, N. R.; Colletti, S. L.; Davies, I. W.; MacMillan, D. W. C.
   * These authors contributed equally to this work.
   Science 2017, 358, 1182–1187
   DOI: 10.1126/science.aap9674
10. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates. 
    Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Org. Lett. 2016, 18, 1706-1709. 
    DOI: 10.1021/acs.orglett.6b00677 
11. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen. 
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Organometallics 2016, 35, 1354-1357. 
    DOI: 10.1021/acs.organomet.6b00126 
12. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates. 
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Beilstein J. Org. Chem. 2015, 11, 2444-2450. 
    DOI: 10.3762/bjoc.11.265 
13. Synthesis of 1,1-Diborylalkenes through a Bronsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron. 
    Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Angew. Chem. Int. Ed. 2015, 54, 15859-15862. 
    DOI: 10.1002/anie.201509218 
14. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes. 
    Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M. 
    Tetrahedron 2015, 71, 65190-6533. 
    DOI:10.1016/j.tet.2015.05.048 
15. Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes. 
    Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M. 
    Chem. Eur. J. 2015, 21, 9666-9670. 
    DOI: 10.1002/chem.201501055 
16. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes. 
    Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Org. Lett. 2015, 17, 2039-2041. 
    DOI: 10.1021/acs.orglet.5b00758 
17. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis. 
    Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Org. Lett. 2015, 17, 1304-1307. 
    DOI: 10.1021/acs.orglett.5b00305 
18. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes. 
    Nagao, K.; Ohmiya, H.; Sawamura, M. 
    J. Am. Chem. Soc. 2014, 136, 10605-10608. 
    DOI: 10.1021/ja506310v 
19. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide. 
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Angew. Chem. Int. Ed. 2013, 52, 11620-11623. 
    DOI: 10.1002/anie.201305973 
20. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes. 
    Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M. 
    J. Am. Chem. Soc. 2012, 134, 8982-8987. 
    DOI: 10.1021/ja302520h 
21. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes. 
    Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Synthesis 2012, 44, 1535-1541. 
    DOI: 10.1055/s-0031-1290818