Dr. Kazunori Nagao (Original papers, Reviews)

Original papers

  1. Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis
    Kakeno, Y.; Kusakabe, M.; Nagao, K.; Ohmiya, H.
    ACS Catal. 2020, 10, 8524–8529.
    DOI: 10.1021/acscatal.0c02849
  2. Reductive Umpolung for Asymmetric Synthesis of Chiral α-Allenic Alcohols
    Kondo, Y.; Nagao, K.; Ohmiya, H.
    Chem. Commun. 202056, 7471–7474.
    DOI: 10.1039/D0CC02619K
  3. Recent Advances in N-Heterocyclic Carbene-Based Radical Catalysis
    Ishii, T.; Nagao, K.; Ohmiya, H.
    Chem. Sci. 2020, 11, 5630–5636.
    DOI: 10.1039/D0SC01538E
  4. Tertiary Alkylations of Aldehydes, Ketones or Imines Using Benzylic Organoboronates and a Base Catalyst
    Sato, Y.; Nakamura, K.; Yabushita, K.; Nagao, K.; Ohmiya, H.
    Bull. Chem. Soc. Jpn. 2020 , 931065–1069.
    DOI: 10.1246/bcsj.20200122
  5. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls
    Ota, K; Nagao, K.; Ohmiya, H.
    Org. Lett. 2020, 22, 3922–3925.
    DOI: 10.1021/acs.orglett.0c01199
  6. Aliphatic Oxaboroles Enabling Remarkable Recognition of Diol
    Arakawa, N.; Nagao, K.; Murakami, R.; Sumida, Y.; Arakawa, H.; Inagaki, F.; Ohmiya, H.
    Bull. Chem. Soc. Jpn. 2020​, 93, 576–580.
    DOI: 10.1246/bcsj.20200007
  7. Allylic Cross-Ccoupling Using Aromatic Aaldehydes as α-Alkoxyalkyl Anions
    Yuasa, A; Nagao, K.; Ohmiya, H.
    Beilstein J. Org. Chem. 202016, 185–189.
    DOI: 10.3762/bjoc.16.21
  8. Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines
    Mitsui, A.; Nagao, K.; Ohmiya, H.
    Org. Lett. 202022, 800–803.
    DOI: 10.1021/acs.orglett.9b04144
  9. Organophotoredox-Catalyzed Decarboxylative C(sp3)–O Bond Formation
    Shibutani, S.; Kodo, T.; Takeda, M.; Nagao, K.; Tokunaga, N.; Sasaki, Y.; Ohmiya, H.
    J. Am. Chem. Soc. 20201421211–1216.
    DOI: 10.1021/jacs.9b12335
  10. N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes
    Ishii, T.; Ota, K.; Nagao, K.; Ohmiya, H.
    J. Am. Chem. Soc. 2019141, 14073–14077.
    DOI: 10.1021/jacs.9b07194
  11. Synergistic N-Heterocyclic Carbene/Palladium Catalyzed Aldehyde Acylation of Allylic Amines
    Ohnishi, N.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    Asian. J. Org. Chem. 2019, 8, 1133–1135.
    DOI: 10.1002/ajoc.201900303
  12. N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes
    Ishii, T.; Kakeno, Y.; Nagao, K.; Ohmiya, H.
    J. Am. Chem. Soc. 2019, 141, 3854–3858.
    DOI: 10.1021/jacs.9b00880
  13. Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis
    Takeda, M.; Mitsui, A.; Nagao, K.; Ohmiya, H.
    J. Am. Chem. Soc. 2019141, 3664–3669.
    DOI: 10.1021/jacs.8b13309
  14. Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions
    Yabushita, K.; Yuasa, A.; Nagao, K.; Ohmiya, H.
    J. Am. Chem. Soc. 2019141, 113–117.
    DOI: 10.1021/jacs.8b11495
  15. Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis
    Haruki, H.; Yasuda, S.; Nagao, K.; Ohmiya, H.
    Chem. Eur. J. 201925, 724–727 (Front CoverCover Profile).
    DOI: 10.1002/chem.201805955
  16. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
    Nagao, N.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2018, 20, 1861–1865.
    DOI: 10.1021/acs.orglett.8b00390
  17. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted γ-Borylallylboranes
    Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 201857, 3196–3199. 
    DOI: 10.1002/anie.201712351
  18. Photoredox-Catalyzed Deuteration and Tritiation of Pharmaceutical Compounds
    Loh, Y.Y*.; Nagao, K*.; Hoover, A. J.; Hesk, D.; Rivera, N. R.; Colletti, S. L.; Davies, I. W.; MacMillan, D. W. C.
    * These authors contributed equally to this work.
    Science 2017, 358, 1182–1187
    DOI: 10.1126/science.aap9674
  19. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates. 
    Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Org. Lett. 201618, 1706-1709. 
    DOI: 10.1021/acs.orglett.6b00677 
  20. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen. 
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Organometallics 201635, 1354-1357. 
    DOI: 10.1021/acs.organomet.6b00126 
  21. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates. 
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Beilstein J. Org. Chem. 201511, 2444-2450. 
    DOI: 10.3762/bjoc.11.265 
  22. Synthesis of 1,1-Diborylalkenes through a Bronsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron. 
    Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Angew. Chem. Int. Ed. 201554, 15859-15862. 
    DOI: 10.1002/anie.201509218 
  23. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes. 
    Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M. 
    Tetrahedron 201571, 65190-6533. 
    DOI:10.1016/j.tet.2015.05.048 
  24. Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes. 
    Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M. 
    Chem. Eur. J. 201521, 9666-9670. 
    DOI: 10.1002/chem.201501055 
  25. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes. 
    Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Org. Lett. 201517, 2039-2041. 
    DOI: 10.1021/acs.orglet.5b00758 
  26. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis. 
    Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Org. Lett. 201517, 1304-1307. 
    DOI: 10.1021/acs.orglett.5b00305 
  27. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes. 
    Nagao, K.; Ohmiya, H.; Sawamura, M. 
    J. Am. Chem. Soc. 2014136, 10605-10608. 
    DOI: 10.1021/ja506310v 
  28. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide. 
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Angew. Chem. Int. Ed. 201352, 11620-11623. 
    DOI: 10.1002/anie.201305973 
  29. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes. 
    Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M. 
    J. Am. Chem. Soc. 2012134, 8982-8987. 
    DOI: 10.1021/ja302520h 
  30. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes. 
    Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Synthesis 201244, 1535-1541. 
    DOI: 10.1055/s-0031-1290818